Rounded corners are not there for air flow. In fact, I think the only time I've seen noticeably rounded corners inside the enclosure was in a transmission line enclosure.
You don't need to direct the air from the back of a driver as the entire cabinet is one common volume. The volume of air 'nearest the vent' is what's going to get moved in and out as the speaker fires
Rounded edges on the baffle, however, are to prevent distortion caused by edge reflections.
All the tricks used in the design of speaker cabinets, full range or otherwise, can be considered negligable on their own, but when used collectively, add up to the holy grail of speaker design - A cabinet that does not colour the sound.
The perfect cabinet does not exist, but by using methods such as those mentioned, speaker designers are getting closer.
I understand that my arguments would be better placed on the SQ forum. In the OP's case I'm not sure if he just wants to make things louder or sound better. Maybe I should have asked that question first.